The National Service Scheme (NSS) Unit of the college is connected to the Savitribai Phule Pune University's Department of National Service Scheme in Pune. 100 NSS Volunteers make to the NSS Unit. To effectively carry out NSS activities, the Unit is composed of three Program Officers: a Chief Program Officer, a Female Program Officer and an Assistant Program Officer. The college principal and vice-principal oversees the operation of the Unit.

The National Service Scheme's motto, "Not Me, But You," serves as inspiration for the unit. The affiliating university has prescribed the Unit's own Calendar of Activities. The calendar's recommended activities are social events with a specific goal of interacting with society. Various national and international holidays are observed, along with cleanliness drives, environmental awareness initiatives, and NSS Volunteers' role in orienting the community. All of the activities listed in the Activity Calendar are carried out by the college's NSS Unit.

In addition to the scheduled calendar, the NSS Unit celebrates the coordinator, MGV Dr. Apoorva Hiray's birthday with a few events like blood donation camps and tree-planting efforts. The idols were gathered by volunteers as part of the Eco-Friendly Immersion of Lord Ganesh project, which aims to stop water pollution. The unit runs health awareness campaigns, such as an awareness campaign for HIV/AIDS. The volunteers distributed masks and took part in a vaccination awareness campaign during the COVID-19 pandemic. The Unit picks a local hamlet each year and carries out welfare operations there. NSS unit is divided into 5 groups on the names of forts of The Great Maratha Empire such as Sinhgadh, Lohgadh, Panhala, Rajgadh, Pratapgadh each of 20 volunteers which includes 2 leaders each from male and female,

Since the NSS Unit is based on the idea of Dignity of Labor, the students involved are referred to as NSS Volunteers. A certificate of participation is given to volunteers upon completion of their two years of NSS service. In accordance with Ordinance 163, which governs affiliating universities, the volunteers' contributions to social work qualify them for grades.

Features of NSS Unit:

• A distinct NSS Department
• A capability to enroll 100 students
• Program Officers who are active and competent.
• Carrying out outreach and social welfare initiatives
• Persistently interacting with the indigenous community
• Prioritize learning about the indigenous culture.
• Recognizing societal issues and coming up with logical fixes for them.
• Enhancing pupils' communicative abilities
• Fostering a sense of teamwork and leadership among the pupils
• Attaining the students' overall growth by instilling various ideals.